Allylpalladium(II) chloride dimer, Pd 58.2% min |
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| Synonyms: Bis(allyl)dichlorodipalladium(II) | |
| Cat. No.: Pd01080 | CAS No.: 12012-95-2 |
| MDL.: MFCD00044874 | Formula: C6H10Cl2Pd2 |
| F.W.365.85 | Purity: |
| Storage: | Sensitivity: |
| Size/Unit | Price | Qty | Availability | Price Total |
|---|---|---|---|---|
| 1g | POA | Enter qty and click checkbox | In stock |
| Catalog Number： | Pd01080 | CAS No.: | 12012-95-2 | |
| MDL: | MFCD00044874 | Formula: | C6H10Cl2Pd2 | |
| F.W.: | 365.85 | Purity: | ||
| Package: | Unit: | g | ||
| Appearance: | Powder | M.P.: | 120° dec. | |
| B.P.: | Density: | |||
| Optical Rotation: | Refractive Index: | |||
| Solubility: | Very soluble in dichloromethane and dichloroethane. Slightly soluble in toluene, insoluble in waterSoluble in chloroform, benzene, acetone and dichloromethane, dichloroethane and methanol. Slightly soluble in toluene. Insoluble in water. | Stability: | ||
| Storage: | Category: | Catalysts | ||
| Application: | Allylpalladium(II) chloride dimer is used as an important catalyst in Heck reaction. It reacts with cyclopentadienyl anion to give cyclopentadienyl allyl palladium. It acts as a precatalyst for asymmetric and cross-coupling catalysis. Further, it is used in the preparation of 1,4-diallyl-1,2-dihydroisoquinolines. It is also employed as a catalyst for greener Buchwald-Hartwig coupling reaction and involved in the synthesis of cationic palladium catalysts. In addition, it takes part in preparation of -heterocyclic carbene-palladium-eta3-allyl chloride complex, which is an efficient catalyst for the Suzuki-Miyaura cross-coupling reactions in synthetic chemistry. | |||