Palladium(II) 2,4-pentanedionate, Pd 35% |
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Synonyms: | |
Cat. No.: Pd01011 | CAS No.: 14024-61-4 |
MDL.: MFCD00000025 | Formula: C10H14O4Pd |
F.W.304.92 | Purity: |
Storage: | Sensitivity: |
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Size/Unit | Price | Qty | Availability | Price Total |
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1g | POA | Enter qty and click checkbox | In stock |
Catalog Number: | Pd01011 | CAS No.: | 14024-61-4 | |
MDL: | MFCD00000025 | Formula: | C10H14O4Pd | |
F.W.: | 304.92 | Purity: | ||
Package: | Unit: | g | ||
Appearance: | Powder | M.P.: | 210° dec. | |
B.P.: | Density: | |||
Optical Rotation: | Refractive Index: | |||
Solubility: | Soluble in benzene and chloroform. | Stability: | ||
Storage: | Category: | Catalysts | ||
Reference: | Wang, Y.; Hu, J.; Cai, Y.; Xu, S.; Weng, B.; Peng, K.; Wei, X.; Wei, T.; Zhou, H.; Li, X.; Liang, G. An Oxygen-Chelate Complex, Palladium Bis-acetylacetonate, Induces Apoptosis in H460 Cells via Endoplasmic Reticulum Stress Pathway Rather than Interacting with DNA. J. Med. Chem. 2013, 56 (23), 9601-9611. Huang, L.; Wang, Y.; Wang, Z.; Chen, F.; Tan, J.; Wong, P. K. Heck Chemistry - a Highly Active Ligand-Free Metal Catalyst System in Situ Generated from PdII Supported on SiO2. Phys. Chem. 2012, 2 (1), 27-34. Hamid, M.; Zeller, M.; Hunter, A. D.; Mazhar, M.; Tahir, A. A.; Redetermination of bis¬(2,4-pentane¬dionato)¬palladium(II). Acta Crystallogr. E 2005, 61 (11), 2181-2183. | |||
Application: | It is used in carbonylation, oligomerization, and as a catalyst precursor for various synthetic organic transformations, for example in the preparation of complexes to efficiently catalyze Heck reaction. Useful in the decarboxylative cross-coupling of arylcarboxylic acids with aryl halides, in the preparation of monodisperse nanoparticles of CuPd alloy and in several cross-coupling reactions. |