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Palladium(II) 2,4-pentanedionate, Pd 34.8% min

Synonyms: Palladium(II) acetylacetonate,Bis(acetylacetonato)palladium(II)
Cat. No.: Pd01010 CAS No.: 14024-61-4
MDL.: MFCD00000025 Formula: C10H14O4Pd
F.W.304.92 Purity:
Storage: Sensitivity:
 
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Catalog Number: Pd01010   CAS No.: 14024-61-4
MDL: MFCD00000025 Formula: C10H14O4Pd
F.W.: 304.92 Purity:
Package: Unit: g
Appearance: Powder M.P.: 210° dec.
B.P.: Density:
Optical Rotation: Refractive Index:
Solubility: Soluble in benzene and chloroform. Stability:
Storage: Category: Catalysts
Reference: Wang, Y.; Hu, J.; Cai, Y.; Xu, S.; Weng, B.; Peng, K.; Wei, X.; Wei, T.; Zhou, H.; Li, X.; Liang, G. An Oxygen-Chelate Complex, Palladium Bis-acetylacetonate, Induces Apoptosis in H460 Cells via Endoplasmic Reticulum Stress Pathway Rather than Interacting with DNA. J. Med. Chem. 2013, 56 (23), 9601-9611. Huang, L.; Wang, Y.; Wang, Z.; Chen, F.; Tan, J.; Wong, P. K. Heck Chemistry - a Highly Active Ligand-Free Metal Catalyst System in Situ Generated from PdII Supported on SiO2. Phys. Chem. 2012, 2 (1), 27-34. Hamid, M.; Zeller, M.; Hunter, A. D.; Mazhar, M.; Tahir, A. A.; Redetermination of bis¬(2,4-pentane¬dionato)¬palladium(II). Acta Crystallogr. E 2005, 61 (11), 2181-2183.
Application: It is used in carbonylation, oligomerization, and as a catalyst precursor for various synthetic organic transformations, for example in the preparation of complexes to efficiently catalyze Heck reaction. Useful in the decarboxylative cross-coupling of arylcarboxylic acids with aryl halides, in the preparation of monodisperse nanoparticles of CuPd alloy and in several cross-coupling reactions.